Season four of Madam Secretary finds Elizabeth (Téa Leoni) trying to achieve diplomacy despite many global enemies poised against her and new political rivals at home. Henry (Tim Daly) takes on a new role at the CIA, which sometimes puts him at cross-purposes with Elizabeth, both professionally and personally. Also this season, their daughters Stevie (Wallis Currie-Wood) continues with her internship in Russell Jackson's (Željko Ivanek) office and Alison (Kathrine Herzer) goes off to college, press secretary Daisy (Patina Miller) has a baby, and the president’s chief of staff Dmitri (Chris Petrovski) returns.
| Title | Time | Price | ||
|---|---|---|---|---|
| 1 | News Cycle | 43:18 | USD 1.99 | Buy on iTunes |
| 2 | Off the Record | 43:22 | USD 1.99 | Buy on iTunes |
| 3 | The Essentials | 43:07 | USD 1.99 | Buy on iTunes |
| 4 | Shutdown | 43:21 | USD 1.99 | Buy on iTunes |
| 5 | Persona Non Grata | 43:26 | USD 1.99 | Buy on iTunes |
| 6 | Loophole | 43:16 | USD 1.99 | Buy on iTunes |
| 7 | North to the Future | 43:20 | USD 1.99 | Buy on iTunes |
| 8 | The Fourth Estate | 43:20 | USD 1.99 | Buy on iTunes |
| 9 | Minefield | 43:21 | USD 1.99 | Buy on iTunes |
| 10 | Women Transform the World | 43:19 | USD 1.99 | Buy on iTunes |
| 11 | Mitya | 43:22 | USD 1.99 | Buy on iTunes |
| 12 | Sound and Fury | 43:20 | USD 1.99 | Buy on iTunes |
| 13 | Reading the Signs | 43:16 | USD 1.99 | Buy on iTunes |
| 14 | Refuge | 43:21 | USD 1.99 | Buy on iTunes |
| 15 | The Unnamed | 43:09 | USD 1.99 | Buy on iTunes |
| 16 | My Funny Valentine | 43:22 | USD 1.99 | Buy on iTunes |
| 17 | Phase Two | 43:22 | USD 1.99 | Buy on iTunes |
| 18 | The Friendship Game | 43:19 | USD 1.99 | Buy on iTunes |
| 19 | Thin Ice | 43:22 | USD 1.99 | Buy on iTunes |
| 20 | The Things We Get to Say | 43:15 | USD 1.99 | Buy on iTunes |
| 21 | Protocol | 43:20 | USD 1.99 | Buy on iTunes |
| 22 | Night Watch | 43:23 | USD 1.99 | Buy on iTunes |
| 23 | Madam Secretary, Season 4 (First Look) | 00:32 | Free | Buy on iTunes |
